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You can use multiple tests. First, check whether each acid/base is a known strong acid or base. For bases, it would be alkaline oxide/hydroxides and for acids, it would be any halogen bonded with hydrogen or an inorganic anion bonded with hydrogen (HNO3). If this isn't the case, I would try to identify weak bases (NH3) or weak acids (anything with a COOH group). Acids are most commonly cations and bases are mostly anions.
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