6c.17

Acidity
Basicity
The Conjugate Seesaw

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Celena Kim 2I
Posts: 106
Joined: Sat Sep 14, 2019 12:17 am

6c.17

Postby Celena Kim 2I » Sat Dec 07, 2019 1:59 pm

How would you determine which is the stronger base?

6C.17 Which is the stronger base, the hypobromite ion, BrO2, or
morphine, C17H19O3N? Justify your answer.

Chem_Mod
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Re: 6c.17

Postby Chem_Mod » Sat Dec 07, 2019 6:09 pm

Hypobromite ion is negatively charged while morphine is neutral. HBrO is neutral while morphine would become positively charged after accepting a proton, which is less favorable. Thus hypobromite is the the stronger base

ATingin_3I
Posts: 51
Joined: Fri Aug 30, 2019 12:17 am

Re: 6c.17

Postby ATingin_3I » Sun Dec 08, 2019 12:23 am

Chem_Mod wrote:Hypobromite ion is negatively charged while morphine is neutral. HBrO is neutral while morphine would become positively charged after accepting a proton, which is less favorable. Thus hypobromite is the the stronger base


if something is a negative ion is it always a stronger base?

ATingin_3I
Posts: 51
Joined: Fri Aug 30, 2019 12:17 am

Re: 6c.17

Postby ATingin_3I » Sun Dec 08, 2019 12:25 am

one of the answers I saw online involved pKb. Could we use this or would we need other values?

005162520
Posts: 101
Joined: Tue Sep 24, 2019 12:17 am

Re: 6c.17

Postby 005162520 » Sun Dec 08, 2019 10:10 am

How would we calculate the pkb value? Would it have to be given?

Chem_Mod
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Re: 6c.17

Postby Chem_Mod » Sun Dec 08, 2019 10:21 am

Anions will not always be stronger bases than some neutral molecules, but you will not be expected to recognize which neutral molecules are stronger bases. Focus on recognizing strong bases (groip 1 and 2 metal cation hydroxides and oxides) as discussed in class. You do not need to be able to calculate pKb for 14A. This will be discussed in 14B


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