Structure of acetic vs formic acid

Acidity
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Hannah Jin 1J
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Joined: Fri Sep 24, 2021 6:42 am

Structure of acetic vs formic acid

Postby Hannah Jin 1J » Mon Jan 17, 2022 12:04 am

Could someone help clarify why, structurally, CH3COOH (acetic acid) is a weaker acid than HCOOH (formic acid)? Thank you!

Jericho Ansay 1C
Posts: 102
Joined: Fri Sep 24, 2021 6:52 am

Re: Structure of acetic vs formic acid

Postby Jericho Ansay 1C » Mon Jan 17, 2022 11:15 am

CH3COOH would be a weaker acid compared to HCOOH because you would consider the atoms bonded to the carboxyl group. If the atom attached to the carboxyl group tends to draw electrons, then the acid is strong. Although CH3COOH and HCOOH are both weak acids, the H atom in HCOOH tends to have more electron withdrawing power than CH3 in CH3COOH, which would make HCOOH (formic acid) the stronger acid.


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