How can we calculate the pH of a solution if we dilute with water?

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Arie Hakimi 1L
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How can we calculate the pH of a solution if we dilute with water?

Postby Arie Hakimi 1L » Thu Feb 23, 2017 1:01 am

How can we calculate the pH of a solution if we dilute with water?

For example, if we assume that we have a weak monoprotic acid (pKa = 5.76, Ka= 1.74x10-6),

How would we calculate the pH after we take a 5 mL sample of 0.010 M weak acid, and dilute it with 45 mL of water?

Lauren Trent 2A
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Joined: Wed Sep 21, 2016 2:56 pm

Re: How can we calculate the pH of a solution if we dilute with water?

Postby Lauren Trent 2A » Thu Feb 23, 2017 2:23 pm

If you're referring to the 14BL study questions, you use the original molarity given (0.010M) and do the M1V1=M2V2 calculation for the dilution to find the molarity of the solution first.
So it would be: (5mL)(0.010M)=(50mL)(M)
Once you solve for the molarity, you follow the same procedure you did for part a of the question and find the concentration of just hydrogen ions with this different molarity of acid using an ICE box, then take the -log of the concentration of H+ ions to find the pH, also like you did for part a.
Hope this helps!


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