Page 1 of 1

Problem 12.69

Posted: Mon Dec 04, 2017 7:57 pm
by Andy Liao 1B
Problem:
12.69 Calculate the pH of each of the following solutions: (a) 0.19 m NH4Cl(aq); (b) 0.055 m AlCl3(aq).

In the solutions manual, the proton transfer equilibria for part (a) is written as NH4+ (aq) + H2O (l) ⇌ H3O+ (aq) + NH3. Why isn't it NH4Cl (aq) + H2O (l) ⇌ H3O+ (aq) + NH3Cl- (aq) instead? Is it incorrect to write it like the latter? Also, for part (b) where does the Al(H2O)6 3+ (aq) come from? The proton transfer equilibria for part (b) is Al(H2O)6 3+ (aq) + H2O (l) ⇌ H3O+ (aq) + Al(H2O5)OH 2+ (aq).

Re: Problem 12.69

Posted: Tue Dec 05, 2017 12:25 am
by Chem_Mod
For (a), the reason they write it out like that is because Cl- in this case acts as a spectator ion. We tend to cancel out spectator ions when discussing reactions, as they don't contribute anything significant to the reaction. For (b), I believe that's an equivalent way to write out AlCl3 when this species is placed in water (it gets hydrated to form this coordination complex). For this problem, the main idea is to understand how to do the equilibrium problem.

Re: Problem 12.69

Posted: Tue Dec 05, 2017 10:14 pm
by 304922790
For part b, the Ka is given as 1.4 x 10^-5. I tried looking for the Ka or Kb (and then converting it to Ka) on the table but I couldn't find it. I was wondering how they got the value.

Re: Problem 12.69

Posted: Tue Dec 05, 2017 10:34 pm
by 304922790
Sorry never mind, I found the value on table 12.8

Re: Problem 12.69

Posted: Tue Dec 05, 2017 10:49 pm
by Magdalena Palavecino 1A
How do you go about solving the problem (a) is you only have Kb of NH3 and it is on the products side? Are you supposed to solve for Ka or should you keep Kb and work to the other side?