How exactly do small, highly charged cations weaken the O-H bonds of water?

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LyahFitzpatrick 2E
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How exactly do small, highly charged cations weaken the O-H bonds of water?

Postby LyahFitzpatrick 2E » Tue Nov 30, 2021 2:05 am

Cations are looking to get rid of electrons, not attract them... how do cations weaken the O-H bond, leading to the eventual release of a hydrogen atom?

cecilia1F
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Re: How exactly do small, highly charged cations weaken the O-H bonds of water?

Postby cecilia1F » Tue Nov 30, 2021 7:48 am

Since highly charged cations have a large positive charge they pull electrons from the bond between oxygen and hydrogen. This weakens the bond allowing for a proton to be broken off and form H3O+ which increases the pH of the solution.

Noah Ho 1F
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Re: How exactly do small, highly charged cations weaken the O-H bonds of water?

Postby Noah Ho 1F » Wed Dec 01, 2021 12:45 pm

These cations often have +2 or even +3 charges, which causes these cations to have a greater electrostatic attraction with O, which has a partial negative charge. This causes the electron distribution of H2O to change, putting more electrons closer to the cation and taking away electrons from the O-H bond, weakening and breaking the O-H bond.

Noa Popko 3I
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Re: How exactly do small, highly charged cations weaken the O-H bonds of water?

Postby Noa Popko 3I » Wed Dec 01, 2021 5:12 pm

The cations have a pretty strong positive charge that is attracted to the slightly negative charge of the O in the water molecules. The electron density is thus pulled from one of the Hs toward the cation, allowing it break off and become H30+ in solution.

Aida Fraser 2I
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Re: How exactly do small, highly charged cations weaken the O-H bonds of water?

Postby Aida Fraser 2I » Wed Dec 01, 2021 5:18 pm

When one proton is released how much does this affect the pH of the solution?


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