Expansion Work

Moderators: Chem_Mod, Chem_Admin

IA_1D
Posts: 105
Joined: Fri Sep 24, 2021 5:28 am

Expansion Work

Postby IA_1D » Sun Jan 23, 2022 9:18 pm

In discussion section, my TA went over that "a system does no expansion work if it expands into a vacuum", can someone further explain that? I am not sure if I am getting a hang of it.

Romi Moore 3k
Posts: 100
Joined: Fri Sep 24, 2021 5:21 am

Re: Expansion Work

Postby Romi Moore 3k » Sun Jan 23, 2022 9:21 pm

To my understanding, it means that since there is no resistance to the gas as it expands, no work is done. When gas expands into a vacuum, the reaction occurs so quickly that there is no heat transfer and no work is done.

Jonathan Sautter 1J
Posts: 101
Joined: Fri Sep 24, 2021 6:02 am
Been upvoted: 1 time

Re: Expansion Work

Postby Jonathan Sautter 1J » Sun Jan 23, 2022 11:52 pm

I believe that in a vacuum, there is nothing for the gas to push against and thus it can't possibly be doing any work if it expands.

Rachel Fox - 3F
Posts: 104
Joined: Fri Sep 24, 2021 6:32 am

Re: Expansion Work

Postby Rachel Fox - 3F » Mon Jan 24, 2022 7:29 pm

If there is a vacuum, that means there are no air molecules present in the surroundings. This means that when a gas expands, there are no air molecules that need to be moved out of the way in order for the pressure to be constant, so no expansion work is being done since there are no air molecules to move for the gas to expand.

Aaron Kwan 3B
Posts: 101
Joined: Fri Sep 24, 2021 6:07 am

Re: Expansion Work

Postby Aaron Kwan 3B » Mon Jan 24, 2022 11:20 pm

Think of work as helping another molecule, such as by moving it. When expanding in a vacuum, there are no other molecules, so you can't possibly help anything.

Coraly De Leon
Posts: 105
Joined: Fri Sep 24, 2021 5:56 am

Re: Expansion Work

Postby Coraly De Leon » Mon Jan 24, 2022 11:55 pm

Hello,
This would be the case because since there is no resistance on the gas as it expands; no external pressure is acting on the gas.


Return to “Phase Changes & Related Calculations”

Who is online

Users browsing this forum: No registered users and 10 guests