Enthalpy and Internal Energy

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Azlyn Hernandez 2E
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Joined: Fri Sep 29, 2023 12:23 pm

Enthalpy and Internal Energy

Postby Azlyn Hernandez 2E » Sun Mar 17, 2024 6:37 pm

Whats the difference between delta H and Delta U?

106052916
Posts: 108
Joined: Fri Sep 29, 2023 11:28 am

Re: Enthalpy and Internal Energy

Postby 106052916 » Sun Mar 17, 2024 6:38 pm

One is the change in internal energy thats dependent on work and heat while the other is heat absorbed or given off by a system. They're very similar but in most cases enthalpy is given to you for a reaction on a table.

Deep Mehta
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Re: Enthalpy and Internal Energy

Postby Deep Mehta » Sun Mar 17, 2024 6:38 pm

Delta H is equal to qp (constant pressure). Delta U on the other hand is q + w, with expansion work taken into account along with delta H.

105561735
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Joined: Sat Oct 09, 2021 5:04 am

Re: Enthalpy and Internal Energy

Postby 105561735 » Sun Mar 17, 2024 10:06 pm

It gets confusing since delta h and delta u both represent changes in energy, but they differ in their definitions, associated conditions (Pressure for delta H and Volume for delta U) and types of energy change they encompass

Emily An 1L
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Joined: Wed Nov 15, 2023 9:20 am

Re: Enthalpy and Internal Energy

Postby Emily An 1L » Sun Mar 17, 2024 10:50 pm

∆H is the enthalpy change in a system and the unit is joules or kilojoules. U is the internal energy of a system refers to the addition of kinetic and potential energy of that particular system and ∆U is the change in internal energy

106062642
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Re: Enthalpy and Internal Energy

Postby 106062642 » Sun Mar 17, 2024 10:51 pm

Under constant pressure, ΔH represents the change in a system's enthalpy, and ΔU represents the change in a system's internal energy. Although they account for different parts of the system's energy, ΔH and ΔU are both essential concepts in thermodynamics that are used to quantify energy changes during chemical reactions and physical processes.

Isabelle Huerta 2I
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Joined: Fri Sep 29, 2023 12:15 pm

Re: Enthalpy and Internal Energy

Postby Isabelle Huerta 2I » Sun Mar 17, 2024 11:04 pm

The main thing when determining the difference between ∆H and ∆U is what they're looking for and what they bring to the system's energy. ∆H is referring to the heat that is being transferred in/out of a system when pressure is a constant (∆P = 0). This value takes into account the internal energy and any work done on/by the system. Now ∆U is only focused on the change of internal energy on the system, regardless of pressure, volume, or work being done/by the system.

Charlotte Norris 2K
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Joined: Fri Sep 29, 2023 11:27 am

Re: Enthalpy and Internal Energy

Postby Charlotte Norris 2K » Sun Mar 17, 2024 11:06 pm

delta U represents the change in internal energy while delta h represents the change in the total heat of a system.

Chris_1234
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Joined: Mon Jan 09, 2023 10:05 am

Re: Enthalpy and Internal Energy

Postby Chris_1234 » Sun Mar 17, 2024 11:09 pm

ΔH measures the heat exchanged during a reaction at constant pressure, while ΔU measures the change in internal energy during a reaction with no change in volume. ΔH is associated with reactions happening in open containers. ΔU is linked to reactions occurring in closed containers, where volume remains constant, like in a bomb calorimeter.


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