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I am not sure if I am understanding your question about the problem completely, but the value given in the table for the standard enthalpy of formation for water is the same value calculated in the solutions manual for the problem. I do not think any of the problems will be as easy as looking at the table and writing down the value for enthalpy given, but rather they will have us utilize one of the three different ways to calculate the enthalpy. In this case, the solution manual used the bond enthalpies to determine the final value, but in the end it is all the same under the same conditions.
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