Hello,
Can anyone tell me why only state properties can be added or subtracted?
Thank you!
State properties
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Re: State properties
Hello!
State properties are properties where the final and initial values do not depend on the path taken to get to the final value. Thus, a change in volume, for instance, does not depend on the many changes that occur between the beginning and the end but only the final and initial values matter. One could have the same change on volume from decreasing volume directly and from increasing then decreasing volume. Other types of functions do not share this property. I hope this helps!
State properties are properties where the final and initial values do not depend on the path taken to get to the final value. Thus, a change in volume, for instance, does not depend on the many changes that occur between the beginning and the end but only the final and initial values matter. One could have the same change on volume from decreasing volume directly and from increasing then decreasing volume. Other types of functions do not share this property. I hope this helps!
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Re: State properties
State properties are not path functions, meaning the difference of the final and initial value are not dependent on the path taken to get from the initial value to the final one. Therefore, you can simply add and subtract values if functions have state properties.
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Re: State properties
Hi, so a state function, like enthalpy, depends solely on the final and initial states. This is in contrast to path functions, where the path taken to reach the final state from the initial state is taken into consideration. It helps to visualize climbers, where their specific path taken to the top of the mountain matters.
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Re: State properties
Hi! For state properties, you only need the final and initial values to find the overall value, which allows you to add and subtract this type of property. I usually think of the mountain analogy to remember the definition of state properties, where it doesn't matter which path you take, as long as you start and end at the same place.
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Re: State properties
State properties can be added or substracted because they only depend on the initial and final values, but not the path taken. For example, if a group of hikers was climbing a mountain, you could say that the change in altitude is a state function because regardless of what path they take, the initial to final altitude won't be affected. On the other hand, the distance they walked is not a state function because they didn't necessarily take a straight path, so the path they choose to take affects the distance traveled.
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