Define Enthalpy
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Define Enthalpy
I am having a little trouble determining exactly what enthalpy is. Specifically it's relation to heat. How would you define enthalpy?
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Re: Define Enthalpy
Enthalpy measures the loss/gain of energy during heat transfer at constant pressure. Since the system is open to the atmosphere, the volume can be adjusted and expansion/compression work is done.
This can be mathematically derived from deltaH = deltaU + P(deltaV).
Since deltaU = q + w --> deltaH = (q+w) + P(deltaV).
Since w = -P(deltaV) --> deltaH = q + (-P(deltaV) + P(deltaV).
These values cancel out and leave deltaH = q.
This can be mathematically derived from deltaH = deltaU + P(deltaV).
Since deltaU = q + w --> deltaH = (q+w) + P(deltaV).
Since w = -P(deltaV) --> deltaH = q + (-P(deltaV) + P(deltaV).
These values cancel out and leave deltaH = q.
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Re: Define Enthalpy
Hi there! Enthalpy is the total heat content in a system. It includes energy between bonds; it's basically all the internal energy of a system. Meanwhile, heat is the energy in transit throughout a system. So enthalpy is measuring the amount of heat. Hope this helps!
Re: Define Enthalpy
enthalpy is the change in heat from a system. a positive enthalpy means that energy was put into the system (ie. to break bonds, endothermic) a negative enthalpy means that energy was released (ie. bonds made, exothermic)
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Re: Define Enthalpy
Positive delta H is an addition of energy (endothermic) and negative delta H is a release of energy (Exothermic). Therefore delta h corresponds to a release/input of heat depending on its sign.
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Re: Define Enthalpy
Enthalpy is the change in heat. It is represented by delta H. A positive enthalpy/delta H is an endothermic reaction and a negative enthalpy/delta H is an exothermic reaction.
Re: Define Enthalpy
Enthalpy is the heat content of a system, and an enthalpy change is the heat released or absorbed by a reaction.
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