Standard Enthalpy of Formation

Moderators: Chem_Mod, Chem_Admin

Julie Mai 1K
Posts: 100
Joined: Fri Sep 24, 2021 6:46 am

Standard Enthalpy of Formation

Postby Julie Mai 1K » Tue Jan 25, 2022 7:30 pm

Hello!

I was wondering why the standard enthalpy of formation for O2 = 0? During lecture, Lavelle solved for the standard enthalpy of combustion of methane as an example for method 3: standard enthalpies of formation and the standard of enthalpy of formation for O2 was 0.

AlexandriaHunt2J
Posts: 100
Joined: Fri Sep 24, 2021 5:38 am

Re: Standard Enthalpy of Formation

Postby AlexandriaHunt2J » Tue Jan 25, 2022 7:34 pm

The standard enthalpy of formation of O2 is zero because the oxygen element naturally exists as O2 in the standard state conditions of 1atm and 298 K. Because O naturally exists as O2, that means no energy is required to form it, so standard enthalpy of formation = 0 kJ/mol.

Ashley Presnell 1C
Posts: 112
Joined: Fri Sep 24, 2021 6:06 am

Re: Standard Enthalpy of Formation

Postby Ashley Presnell 1C » Tue Jan 25, 2022 9:50 pm

Lavelle mentioned that the standard enthalpy of formation of elements in their natural state like O2 for oxygen or N2 for nitrogen would be 0. Since it is the naturally more stable form of the element, it doesn't require energy to form it, but rather would require energy to form a different structure of it that is not as stable as it would favor the formation of O2.

Maham Kazmi 2J
Posts: 113
Joined: Fri Sep 24, 2021 5:44 am

Re: Standard Enthalpy of Formation

Postby Maham Kazmi 2J » Tue Jan 25, 2022 11:57 pm

Hi! I remember that Dr. Lavelle explained it in a way where the standard enthalpy of formation is a reference point. It's like how we call sea level 0 altitude regardless of whether or not it truly is. It allows us to compare other values. So in general, any molecule in its natural state would have a standard enthalpy of formation of 0.

Yuhan Sun
Posts: 53
Joined: Mon Jan 03, 2022 9:01 pm

Re: Standard Enthalpy of Formation

Postby Yuhan Sun » Wed Jan 26, 2022 12:09 pm

The definition of standard enthalpy of formation is the enthalpy change of one mole from a substance in its elements in their most stable form.
O2, N2, H2 etc. these are just the most stable form from its elements. So the amount of change is 0.

405479701
Posts: 98
Joined: Fri Sep 24, 2021 5:03 am
Been upvoted: 1 time

Re: Standard Enthalpy of Formation

Postby 405479701 » Wed Jan 26, 2022 1:05 pm

In the lecture, we learned the standard enthalpy of formation of any element in its natural state is 0. For example, N2 for nitrogen or 02 for oxygen would be 0.

Lesley Kim 1K
Posts: 50
Joined: Mon Jan 03, 2022 11:06 am

Re: Standard Enthalpy of Formation

Postby Lesley Kim 1K » Thu Jan 27, 2022 3:57 pm

The standard enthalpy of formation is zero as O2 requires no energy in order for the molecule to exist as O2 is already oxygen's natural state or its most stable form.

Achyutha Kodavatikanti_3H
Posts: 51
Joined: Mon Jan 03, 2022 9:33 pm

Re: Standard Enthalpy of Formation

Postby Achyutha Kodavatikanti_3H » Thu Jan 27, 2022 5:11 pm

standard enthalpy of formation of diatomic elements like O2 is 0 because that's how they exist in nature. there is no energy needed to form O2.

Nicole Ton 3C
Posts: 111
Joined: Fri Sep 24, 2021 6:51 am

Re: Standard Enthalpy of Formation

Postby Nicole Ton 3C » Fri Jan 28, 2022 2:19 am

The standard enthalpy of formation is the standard reaction enthalpy for the formation of a mole of the substance from their element in the most stable form. Standard enthalpy of formation is under standard condition and using elements in their standard state. Oxygen's most stable form is O2, so O2's standard enthalpy of formation is 0.


Return to “Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)”

Who is online

Users browsing this forum: No registered users and 5 guests