Textbook Question 4A.13

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kaela_losekoot_2A
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Textbook Question 4A.13

Postby kaela_losekoot_2A » Thu Mar 14, 2024 12:23 am

A constant-volume calorimeter was calibrated by carrying out a reaction known to release 3.50 kJ of heat in 0.200 L of solution in the calorimeter (q = -23.50 kJ), resulting in a temperature rise of 7.32 C. In a subsequent experiment, 100.0 mL of 0.200 m HBr(aq) and 100.0 mL of 0.200 m KOH(aq) were mixed in the same calorimeter and the temperature rose by 2.49 C. What is the change in the internal energy of the reaction mixture as a result of the neutralization reaction?

I understand how to calculate heat capacity, and I know multiplying that heat capacity by the change in temperature gives the correct answer. However, the equation for q is q=nCdeltaT, so I don't understand why we don't consider moles in the calculation?

Also, if we do include moles would the moles be the combined moles of the two reactants?
Thank you

audrey 1A
Posts: 42
Joined: Fri Sep 29, 2023 9:41 am

Re: Textbook Question 4A.13

Postby audrey 1A » Thu Mar 14, 2024 12:39 am

The question has a constant v so you don't need to worry about n. I hope that helps!


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