Spontaneous Reactions
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Re: Spontaneous Reactions
A spontaneous chemical reaction is exergonic when it is spontaneous. This means that work is being done by the system on its surroundings, and the ΔG in this case from ΔG = ΔH = TΔS will be negative.
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Re: Spontaneous Reactions
Spontaneous reactions are usually exergonic, meaning that energy flows from the system to the surroundings. The energy released, free energy, can be used to do work.
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Re: Spontaneous Reactions
Are there rules for enthalpy and entropy when it comes to whether a reaction is spontaneous or not?
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Re: Spontaneous Reactions
There are rules for enthalpy and entropy, but it depends on the conditions:
If delta H is + and delta S is -, then delta G is nonspontaneous at ALL temperatures
If delta H is - and delta S is -, then delta G is spontaneous at low temperatures
If delta H is + and delta S is +, then delta G is spontaneous at high temperatures
If delta H is - and delta S is +, then delta G is spontaneous at ALL temperatures
If delta H is + and delta S is -, then delta G is nonspontaneous at ALL temperatures
If delta H is - and delta S is -, then delta G is spontaneous at low temperatures
If delta H is + and delta S is +, then delta G is spontaneous at high temperatures
If delta H is - and delta S is +, then delta G is spontaneous at ALL temperatures
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