finding heat capacity using q=cΔT

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Felicia Fong 2G
Posts: 31
Joined: Sat Jul 22, 2017 3:00 am

finding heat capacity using q=cΔT

Postby Felicia Fong 2G » Sat Feb 10, 2018 3:00 pm

This question is from the 2011 Midterm.
Q1a) The enthalpy of combustion of benzoic acid is -3227 kJ/mol. When 1.453g of benzoic acid was burned in a calorimeter, the temp increased by 2.265 degrees C. What is the heat capacity of the calorimeter?

The solution is:
q=CcalΔT
Ccal=-(mol benzoic acid)(-3227 kJ/mol benzoic acid)/2.265 degrees C
=16.95 kJ/degrees C

Why is there a negative in front of the mol of benzoic acid? Why do you multiply the number of moles of benzoic acid by the enthalpy of combustion instead of dividing? I thought the equation with moles is q=nCcalΔT

Justin Folk 3I
Posts: 43
Joined: Wed Sep 21, 2016 2:56 pm

Re: finding heat capacity using q=cΔT

Postby Justin Folk 3I » Sat Feb 10, 2018 3:06 pm

The heat capacity is defined as ENERGY per TEMPERATURE

Ethan Vuong 3G
Posts: 51
Joined: Fri Sep 29, 2017 7:07 am

Re: finding heat capacity using q=cΔT

Postby Ethan Vuong 3G » Sat Feb 10, 2018 3:09 pm

Since you are looking for the specific heat capacity, you wouldn't be solving for q, but for Ccal. Therefore, you would divide q by delta T. I am unsure of where the negative comes from though.

Angela 1K
Posts: 80
Joined: Fri Sep 29, 2017 7:05 am

Re: finding heat capacity using q=cΔT

Postby Angela 1K » Tue Feb 13, 2018 5:36 pm

It is negative because the q of the calorimeter is going to be the negative of the q of the reaction, which is what we use in the equation.

Hope that makes sense.


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