Why are the energies of the different interactions Dr. Lavelle talked about in class negative?
For example, the energy of an ion-ion interaction is -250 kJ/mol. I am a little confused why it's a negative number and not a positive one.
Energy of Intermolecular Forces
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Re: Energy of Intermolecular Forces
They are all negative because it is taking energy from the system to form bonds. This takes away energy thus a negative energy.
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Re: Energy of Intermolecular Forces
Energy is required to form bonds. Because these are forming attractions with other molecules, this formation of bonds implies an exothermic reaction, which relates to a negative energy of the system
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Re: Energy of Intermolecular Forces
It seems a little bit counterintuitive, but forming bonds requires energy. Creating a bond is bringing 2+ atoms into a more stable position. Thus, breaking the bond is where energy is absorbed whereas forming bonds is where energy is released.
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Re: Energy of Intermolecular Forces
Breaking bonds generally requires an addition of energy. The opposite, forming bonds, is a release of energy which explains the negative number.
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Re: Energy of Intermolecular Forces
you need energy to form bonds and energy is released when bonds are broken
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