Delta U for Reversible and Irreversible
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Delta U for Reversible and Irreversible
Is delta U equal to zero for both reversible and irreversible reactions? If not, under what conditions is delta U equal to zero?
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Re: Delta U for Reversible and Irreversible
Delta U is equal to 0 when the work done by the system is equally replaced by heat being added into the system.
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Re: Delta U for Reversible and Irreversible
Also, deltaU = 0 for the isothermal reaction(or compression) of an ideal gas.
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Re: Delta U for Reversible and Irreversible
In our class, (delta)U=0 for all reversible reactions. Irreversible ones will not equal zero if there is any expansion work. So if deltaV is not zero, there is energy transferred in the system.
Re: Delta U for Reversible and Irreversible
It is also important to note that when there is an isothermal, irreversible "free expansion," this implies that the system does not do any expansion work, and therefore w=0.
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