qp and qv
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Re: qp and qv
By definition, enthalpy is the amount of heat absorbed/released at a constant pressure. So that means that delta H only equals qp rather than qv.
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Re: qp and qv
Enthalpy in this case is referring to heat at a specific pressure, not a specific volume. Thus, the p subscript instead of v.
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Re: qp and qv
Enthalpy, which is represented by delta(h), is heat at a constant pressure. Heat is represented by "q", and because the pressure is constant, it will have the subscript "p" for pressure, rather than "v" for volume.
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Re: qp and qv
When volume is not constant, the gas is either expanding or compressing, so there is some work done. Therefore, that energy from work contributes to the delta H and must be factored in.
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Re: qp and qv
It's simply that the definition of enthalpy is heat at a constant pressure. That's how it's defined as a function.
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Re: qp and qv
If the heat transfer is occurring while pressure is changing, q is not equal to change in enthalpy, since the change in enthalpy is defined at a constant pressure. Therefore, change in enthalpy only equals q when pressure is held constant: qp = change in enthalpy.
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