test problem 4A.5 continued
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test problem 4A.5 continued
Why does this problem use for an irreversible expansion but w=-nRTln(V2/V1) for a reversible expansion?
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Re: test problem 4A.5 continued
You always use w=Pex x (delta)V for an irreversible expansion because the change in volume is measurable. For a reversible process you use the other equation because the change in volume is infinitestimally small. For the reversible expansion, pressure falls as the volume increases which is reflected by the nRT part of the equation from PV=nRT.
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Re: test problem 4A.5 continued
If you look back at the notes, you can see Dr. Lavelle derive the equation for the reversible expansion. Additionally, it is also in the book.
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Re: test problem 4A.5 continued
I'm not exactly sure of the derivations for both, but I would just correlate each equation to irreversible and reversible respectively. Just know which of those equations to use given its reversible or not.
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