I'm having some trouble with this Sapling problem. I know that Cl2 has a charge of 2- so the coordination compound must have a charge of 2+, so would the charge of Co be 3+?
Give the oxidation state of the metal species in the complex [Co(NH3)5Cl]Cl2
Oxidation Number
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Re: Oxidation Number
Yes, you are correct. +3 is the oxidation state of the Co. NH3 is neutral and since the charge of two chlorine outside is -2 the compound charge must be +2. Therefore, since Cl inside has a charge of -1 you set this equation: X -1 = +2. The X aka the oxidation of Co is +3
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Re: Oxidation Number
Yes you're correct for accounting for both the ligands inside and outside of the coordination sphere.
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Re: Oxidation Number
Yes you are exactly correct. I think a good way to think about it is just to remember that the overall charge of the cation and anion should equal zero. You can do:
X + (0)(NH3) + (-1) + 2(-1) = 0
where x is the unknown oxidation number for cobalt, NH3 is a neutral atom, and chlorine (a halogen) is known to have a -1 oxidation number. This would apply to any other ligand and complex ion problem too! Hope this helps.
X + (0)(NH3) + (-1) + 2(-1) = 0
where x is the unknown oxidation number for cobalt, NH3 is a neutral atom, and chlorine (a halogen) is known to have a -1 oxidation number. This would apply to any other ligand and complex ion problem too! Hope this helps.
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Re: Oxidation Number
Hi!
Correct, you are right. From my understanding, NH3 is neutral therefore the charge of two chlorine outside would be -2. The compound charge must then be +2 for everything to make sense. That is why, in this case, Cl has a charge of -1 you set this equation: X -1 = +2. It may sound confusing but once you get it, it will make a lot more sense promise.
Correct, you are right. From my understanding, NH3 is neutral therefore the charge of two chlorine outside would be -2. The compound charge must then be +2 for everything to make sense. That is why, in this case, Cl has a charge of -1 you set this equation: X -1 = +2. It may sound confusing but once you get it, it will make a lot more sense promise.
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- Joined: Wed Sep 30, 2020 9:42 pm
Re: Oxidation Number
An easy way for me to find the oxidation number is to find the anion charge first and determine what the overall charge of the coordinate compound is. Whether it is 0 or -2, -1, etc. Using that to find the oxidation number so that the charges in the compound matches the overall charge.
Re: Oxidation Number
Try treating the atoms inside the molecule as one entire molecule to better visualize such as NaCl. We know Cl is -1 and as a whole it is negative so Na must be +1. Try thinking like this so if Cl2 add up to -2 then the brackets should be +2 and then break it down further to find the TM cation charge.
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