Atomic Spectra- Question 1.15  [ENDORSED]

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Kaitlin_Ryan_ 3K
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Atomic Spectra- Question 1.15

Postby Kaitlin_Ryan_ 3K » Thu Oct 06, 2016 3:55 pm

When solving this problem, I ran into a problem when trying to determine which n value should be used for E(final) and which should be solved for E(initial).

When I plugged in n=1 for E(final) and solved for n, I came up with a decimal energy level, which is not possible.

When I plugged in n=1 for E(initial), I got n=3, which is the correct answer.

Why do I need to plug in n=1 for E(initial) and not E(final) to obtain the correct answer to this question?

Aileen Nguyen 3N
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Re: Atomic Spectra- Question 1.15  [ENDORSED]

Postby Aileen Nguyen 3N » Thu Oct 06, 2016 4:32 pm

I solved this problem using the Rydberg equation instead of the bohr frequency condition.

You solved the n1=1 so for a line that's 102.6 nm you use the formula v=c/(lambda) = 2.922 x10^15 s^-1

Then use the Rydberg to solve for n2 which would give you n2=3

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Re: Atomic Spectra- Question 1.15

Postby 104822659 » Thu Oct 06, 2016 11:18 pm

How did you guys know that n=1 in this problem?

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Re: Atomic Spectra- Question 1.15

Postby Lauren_Bui_1A » Thu Oct 06, 2016 11:26 pm

In the question it states "In the ultraviolet spectrum of atomic hydrogen..."
The ultraviolet spectrum is the Lyman series, so n final=1.

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