Reversible vs irreversible process
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 9
- Joined: Wed Sep 21, 2016 2:58 pm
Reversible vs irreversible process
Can someone explain the difference between a reversible and irreversible process?
-
- Posts: 32
- Joined: Wed Sep 21, 2016 2:58 pm
- Been upvoted: 1 time
Re: Reversible vs irreversible process
In an irreversible reaction, the reactants convert to products, but the products cannot convert back to reactants (think of combustion, in which oxygen gas is burned with a compound; this process cannot be reverted/ reversed).
In a reversible reaction the reactants and products are never fully consumed; they are each constantly reacting and being produced (think of this as a reaction at equilibrium, in which the reaction does not stop, but conversions/reactions do not appear to be taking place because the products and reactants are forming at equal rates). Reversible reactions can occur, for example, when a system is at equilibrium and pressure(external) = pressure(internal); essentially when a system is at equilibrium.
In a reversible reaction the reactants and products are never fully consumed; they are each constantly reacting and being produced (think of this as a reaction at equilibrium, in which the reaction does not stop, but conversions/reactions do not appear to be taking place because the products and reactants are forming at equal rates). Reversible reactions can occur, for example, when a system is at equilibrium and pressure(external) = pressure(internal); essentially when a system is at equilibrium.
-
- Posts: 11
- Joined: Fri Jul 22, 2016 3:00 am
Re: Reversible vs irreversible process
Building off of what Melanie said, if you were to theoretically be in a state of equilibrium between the pressure of a gas in a system with that of the external pressure. An infinitesimally small change in external pressure will change the the pressure in the inside in such a way that it can literally be reversed with the same infinitesimal change in the opposite direction. However, with an irreversible process, the differing pressures are large enough quantities that an extremely small change in pressure inside the gas or outside wouldn't change the state of the system. The bottom line is that reversible processes are considered the "better" of the two in the sense that you get more work out a system that undergoes a reversible process.
Return to “Concepts & Calculations Using First Law of Thermodynamics”
Who is online
Users browsing this forum: No registered users and 11 guests