Difference between delta H and delta U

Moderators: Chem_Mod, Chem_Admin

Lucia H 2L
Posts: 43
Joined: Mon Nov 14, 2016 3:00 am
Been upvoted: 1 time

Difference between delta H and delta U

Postby Lucia H 2L » Fri Jan 12, 2018 8:04 pm

What is the difference between delta H and delta U? and q for that matter

Sirajbir Sodhi 2K
Posts: 47
Joined: Sat Jul 22, 2017 3:00 am

Re: Difference between delta H and delta U

Postby Sirajbir Sodhi 2K » Fri Jan 12, 2018 8:17 pm

Delta H is the change in enthalpy and Delta U is the change in internal energy. Internal energy is the amount of energy a system has. However, we must realize that a system doesn't exist in a vacuum. Rather, there must be some sort of change in volume/pressure because of the presence of a system. If we hold pressure constant, as it often is when a system is introduced, volume must change (we know this from gas laws). This leads us to the concept of enthalpy which is, in essence, a convenient way to MEASURE a system's internal energy at a constant pressure.

The following equation relates the two quantities:

ΔH = ΔU + PΔV

Q is heat -- and is equal to enthalpy at a constant pressure.

Sophie 1I
Posts: 51
Joined: Fri Sep 29, 2017 7:04 am

Re: Difference between delta H and delta U

Postby Sophie 1I » Sat Jan 13, 2018 4:42 pm

Delta H is the change in enthalpy which is equal to change in U +P*change in V and the delta U is the change in internal energy of the system.
q is the heat of the system.


Return to “Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)”

Who is online

Users browsing this forum: No registered users and 4 guests