sign of entropy

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Jack Papciak 2F
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Joined: Fri Sep 29, 2017 7:06 am

sign of entropy

Postby Jack Papciak 2F » Mon Jan 29, 2018 4:26 pm

How do I know whether the entropy has a "+" or a "-"?

Grace Boyd 2F
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Joined: Thu Jul 27, 2017 3:01 am

Re: sign of entropy

Postby Grace Boyd 2F » Mon Jan 29, 2018 4:29 pm

As Dr. Lavelle explained today in lecture, the sign of entropy depends on the direction of heat flow. If the system loses heat, the entropy will have a negative sign in front of it. If the surroundings gain heat, the entropy will have a positive sign. I hope this helps!

Alyssa Pelak 1J
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Re: sign of entropy

Postby Alyssa Pelak 1J » Mon Jan 29, 2018 6:00 pm

Additionally, entropy is positive when the reaction spontaneous. It means that the system has more possible states. Entropy is negative when the system has less possible states.

Lauren Seidl 1D
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Re: sign of entropy

Postby Lauren Seidl 1D » Mon Jan 29, 2018 7:45 pm

Also, if delta entropy equals zero then the reaction is at equilibrium.

Leanne Wong 1H
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Re: sign of entropy

Postby Leanne Wong 1H » Wed Jan 31, 2018 4:26 am

You determine the sign of entropy by the direction of heat flow.

RohanGupta1G
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Re: sign of entropy

Postby RohanGupta1G » Wed Jan 31, 2018 8:43 am

Direction of heat flow determines the sign as well as whether or not the reaction is spontaneous.

Jingyi Li 2C
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Re: sign of entropy

Postby Jingyi Li 2C » Wed Jan 31, 2018 10:25 am

The sign of entropy indicates the direction of heat flow.

Amanda Wu 2C
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Joined: Sat Jul 22, 2017 3:00 am

Re: sign of entropy

Postby Amanda Wu 2C » Wed Jan 31, 2018 3:59 pm

The sign of entropy is indicative of the heat flow in or out of the system. A system in which heat flows out to the surroundings will have a negative entropy whereas a system in which heat flows in from the surroundings will have a positive entropy.

Josh Moy 1H
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Re: sign of entropy

Postby Josh Moy 1H » Wed Jan 31, 2018 10:21 pm

sign of entropy depends on flow of heat

melissa carey 1f
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Re: sign of entropy

Postby melissa carey 1f » Thu Feb 01, 2018 2:06 pm

Additionally, during a process of expansion entropy increases as there are more possible states.

JamesAntonios 1E
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Re: sign of entropy

Postby JamesAntonios 1E » Thu Feb 01, 2018 2:12 pm

Jack Papciak 2F wrote:How do I know whether the entropy has a "+" or a "-"?


It depends on the the ratio of final to initial temperature, volume, and/or pressure. You can logically think about by analyzing whether the number of microstates is increasing or decreasing, which can give an indication to what the sign should be.

Luke Bricca 1H
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Joined: Fri Sep 29, 2017 7:06 am

Re: sign of entropy

Postby Luke Bricca 1H » Sun Feb 04, 2018 9:29 am

Additionally, in connection with Gibbs free energy, if the sign of the delta G is negative, the reaction is spontaneous and favorable.


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