The Third Law
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 51
- Joined: Fri Sep 29, 2017 7:04 am
-
- Posts: 60
- Joined: Thu Jul 27, 2017 3:01 am
Re: The Third Law
The third law of thermodynamics states that entropy of a perfect crystal is zero when the temperature is zero Kelvin. If it isn't a perfect crystal or if it is at a different temperature there will be residual entropy.
-
- Posts: 60
- Joined: Thu Jul 27, 2017 3:01 am
Re: The Third Law
A perfect crystal only has one microstate so w=1. When you plug 1 into the equation S=kb*ln(w) and solve, you get zero.
-
- Posts: 40
- Joined: Fri Sep 29, 2017 7:07 am
- Been upvoted: 1 time
Re: The Third Law
we know the micro state is w=1 because there exists no movement at 0 Kelvin therefore resulting in entropy equal to 0.
Who is online
Users browsing this forum: No registered users and 1 guest