closed vs isolated
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Re: closed vs isolated
I don't think they are unless it says otherwise. I do know that if it's a bomb calorimeter volume stays constant
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Re: closed vs isolated
No, specifying the system as closed or isolated doesn't mean that the pressure or volume are constant.
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Re: closed vs isolated
No, closed is just where matter can't escape. isolated is where neither matter nor internal energy can escape
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Re: closed vs isolated
The text has to say if it is under constant pressure or volume. I don't think assuming is good enough.
I also have a question.
When the text says "ideal", does that mean constant pressure and volume because ideal would be 1 atm and 1M?
I also have a question.
When the text says "ideal", does that mean constant pressure and volume because ideal would be 1 atm and 1M?
Re: closed vs isolated
You don't want to assume anything, but if the question says that the reaction happens in a bomb calorimeter, you can assume it's constant volume.
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Re: closed vs isolated
Knowing whether a system is closed or isolated only tells you whether it can exchange energy with its surroundings or not. Don't assume that pressures and volumes are constant unless the problem specifically states that they are.
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Re: closed vs isolated
No, unless the problem specifies. When given just "closed" or "isolated" that deals with energy exchange (or lack thereof).
Re: closed vs isolated
An example would be the expansion of a balloon. Say the pressure outside the balloon decreased, the volume of the balloon would increase as it expanded. However, it is still a closed system because the balloon never actually lost any matter, it just reacted to outside conditions.
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Re: closed vs isolated
Yes, heat transfer does happens because they system is doing work and losing energy. This energy is replaced by heat flow, q, into the system.
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