Sign for compression vs expansion
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 43
- Joined: Wed Nov 16, 2016 3:03 am
Sign for compression vs expansion
When using the equation for w=-P
is it true that for compression the answer will be positive and for expansion it will be negative?
-
- Posts: 71
- Joined: Fri Sep 29, 2017 7:04 am
- Been upvoted: 1 time
Re: Sign for compression vs expansion
Yes, compression is a negative delta V, which multiplied by negative P, gives you a positive value for work.
Same methodology for expansion, positive delta V.
Same methodology for expansion, positive delta V.
-
- Posts: 49
- Joined: Fri Sep 29, 2017 7:07 am
Re: Sign for compression vs expansion
To determine the sign, think about if the work is done to the system or by the system. W is positive if work is done by the system, and negative if work is done on the system
-
- Posts: 36
- Joined: Fri Sep 29, 2017 7:04 am
Re: Sign for compression vs expansion
Yes, that is correct. You can assume pressure is 1 atm and then plug in values for delta V to check. If you compress something, Vf-Vi will be negative, so the two negative signs will combine to make a positive value. Delta V is positive for expansion, so the value will end up being negative.
-
- Posts: 53
- Joined: Fri Sep 29, 2017 7:06 am
Return to “Phase Changes & Related Calculations”
Who is online
Users browsing this forum: No registered users and 0 guests