## CNS- formal charge

$FC=V-(L+\frac{S}{2})$

Michelle Shin 4B
Posts: 50
Joined: Thu Jul 25, 2019 12:17 am

### CNS- formal charge

In the lecture, we went over how the best version of CNS- is when the formal charge of -1 is on the S. Why is the formal charge of -1 on sulfur and not on nitrogen?

Hannah Lee 2F
Posts: 117
Joined: Thu Jul 11, 2019 12:15 am

### Re: CNS- formal charge

I don't recall seeing that structure in my notes, but assuming that carbon is the central atom, the most electronegative atom should carry the negative formal charge. In this case, N should have the negative charge since it's more electronegative than sulfur. So the most stable structure would go: S = C = N.

KaitlynBali_4B
Posts: 51
Joined: Fri Aug 02, 2019 12:16 am

### Re: CNS- formal charge

Yes, the example in the book also shows that the most stable structure is S = C = N. Nitrogen does have a -1 formal charge in this structure, and carbon and sulfur both have formal charges of 0. This example is on page 85 in the book. In the structure C = N = S, the formal charges are -2 for C, +1 for N, and 0 for S, and the structure C = S = N has the charges -2 for C, +2 for S, and -1 for N. In these examples, S never has a formal charge of -1.

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